- Erwyd Howells collection: copy of the earmark record book of Llanddewi Brefi and surrounding areas; the work of Edward (Eddie) James, Ty'n syffe, a servant on the Graig farm, Llanddewi nd
- Richard Jones's tone book, Mathan candol, Boduan,1839, from the collection of John Hughes (1847-1936) 1839
- Randall Holme II (1601-1659), herald painter and genealogist: pedigree of John Edwards of Stanstey 1654 (NLW MS 24200)
- Deed for a piece of land on the road from St Breuial/Bremall [?Briavel] to Strugull [Chepstow] 1523 (NLW Deeds 1963)
- Gregynog Estate: records rel to the Morville Hall estate, Shropshire, inherited by Arthur Blayney in 1759, comprising account books for 1763-72 ('Accounts with Mr Guest Shropshire'), 1772-77 ('Shropshire Accounts'), and 1777-86 ('Mr Guest's Cash Accounts); Gregynog Estate rentals 1763-1786
- Elizabeth Bower (fl1829), wife of John Sheldon Bower, of Crosby, Liverpool: account of an excursion to North Wales and Cheshire 1829 (NLW MS 24197)
- Court leet records (Wyndham Powell records) 19th cent
- A petition signed by 390,296 women in Wales, led by Annie Hughes-Griffiths, calling on the United States of America to join and lead the League of Nations, together with a specially built chest for transport to Washington DC. Title on the chest: 1923-1924. Appeal from the women of Wales to the women of the United States of America / The Memorial from the Women of Wales to the women of the United States of America (Deiseb Heddwch Menywod Cymru/Women's Peace Petition) 1923-1924
- Charm by a 'dyn hysbys' (cunning man) to cure from illness "the woman Ingram of Gilfach, Llanwnog, Caersws, Mont", inserted in an envelope inscribed 'Mrs Ingram', together with its original bag and photographs of these items nd (NLW MS 24203)
- Framed pedigree of William Griffith, repainted in watercolours on paper with armorial crests and circled names and inscribed 'William Gruffyth esquier, Justice of the peace and corum of the Cittie and Libertie of Westminster and of the Countie of Middlesex And Sergeant of Arms to the King' 16th-17th cent (NLW MS 24202G)
- Dorothy Noel 'Dorf' Bonarjee (1894–1983), Indian poet and artist: papers, incl a notebook containing poetry 1915-1983 (BONARJEE)
- Martin Tinney Gallery, Cardiff: archive incl cards, catalogues, exhibition lists, artists' letters, gallery adverts, press articles on the gallery and exhibitions, and art fair catalogues 1980-2022
- Rt Hon Mark Drakeford (b1954), First Minister of Wales: papers, incl material rel to the UK withdrawal from the European Union, and documents reflecting Welsh Government relations with the Westminster and devolved governments 202-2023
- Dolgorfan Estate, Kerry: material incl financial and legal papers, sale catalogues and photographs 1892-1972
- Monmouthshire Constabulary: collection of Victorian police notebooks, original charge sheets and ephemera 1867-1879 (NLW ex 3096)
- Papers rel to the musician and singer Sianed Elin Jones 1980-2022
- Welsh Salmon and Trout Angling Association: archive, incl minutes of meetings, annual reports, photographs, membership records and official papers nd
- Lucy Amelia Penny (née Powys): collection of letters, photographs and family ephemera accumulated by Penny, the youngest child of the Reverend C. F. Powys, vicar of Montacute, Somerset, and Mary Cowper Johnson 20th cent
- Seven autograph letters, signed 'David Jones', dated 23 August 1961 - 28 April 1967, to Bryn Griffiths (6) and the editor of The Tablet (1) 1961-1967 (NLW MS 24183F)
- Wynnstay Estate, Wrexham: mid 18th-century commonplace book, probably the property of and inscribed by a member of the Williams-Wynn family of Wynnstay, containing poetry, incl the astronomical poem ‘On seeing a Comet, in the Year 1769. A Night-scene’, and loosely-inserted leaves (3) with medical recipes; printed ephemera 19th cent
- Reverend Francis Taynton (1799-1869/70): manuscript pocket book, compiled and inscribed whilst he was incumbent of the parishes of Ystradowen and Talygarn, Vale of Glamorgan, and later a resident of Cowbridge; further records rel to his horse dealings, dates and locations of his tours, operas, concerts and plays attended and watched 1811-1870 (NLW MS 24205)
- Rev. Canon Jennifer Wigley (fl1988-2017), Rector of Radyr: scrapbook, sermons and records rel to the campaign for the ordination of women in the Church in Wales 1988-2017
- Charles I (1600-1649), King of Great Britain and Ireland: document, dated 28 December [1641], to Henry Somerset, fifth Earl of Worcester, ordering the High Sheriff of Monmouth and the officers beneath him to offer all assistance to the Earl should "...any Abuse outrage or Tumult..." be attempted against him. The document was signed two weeks before Charles I's departure from London for Oxford, where he was to raise the flag and thus initiate the Civil War 1641 (NLW MS 24183F)
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