- Meg Ellis, politician: papers 1950- (Papurau Meg Ellis Papers)
- Peter Finch, poet and author: papers 1947- (Peter Finch Papers)
- Sabine Baring-Gould, writer: autographed manuscript study of 'St Cuby of Duloe' 1900 (NLW MS 24041)
- David Jones, clergyman: diary 1798 (NLW MS 24020A)
- Gwyneth Lewis, poet: papers 1959- (Gwyneth Lewis Papers)
- William Nethercoat: journal of a tour in Wales and Ireland 1812 (NLW MS 24023)
- Pedigree and achievement of Lewis Powell of Lamphey, Pembrokeshire, with one hundred and twenty coats of arms, all emblazoned and painted 1630 (NLW MS 24018G)
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