- John Emyr, author: corresp 1970-91 (NLW MS24005E)
- David Lloyd George, 1st Earl Lloyd George of Dwyfor, statesman: manuscripts notes concerning the Honours System in Britain 1922 (NLW MS 23981)
- Augustus Edwin John, painter and etcher and Dorelia John, painter: letters to Mavis and Tristan de Vere Cole 1934-68 (NLW MS 24007, NLW MS 24008, NLW MS 24009)
- Richard Arthur Lloyd Livsey, Baron Livesey of Talgarth and politician: political papers 1935-2010 (Lord Livsey's Papers)
- Jan Morris, author: corresp and personal papers incl a transcript of memoirs 'Conundrum' (Additional: Jan Morris Papers)
- John Tripp, poet, journalist and literary editor of Planet: unpublished poems, short stories, script of a radio play and other draft documents 1969-75 (NLW MS 24013)
- Wales Federation of Young Farmers Clubs: minutes, correspondence, reports, photographs and publications (Wales Young Farmers Club Papers)
- Wales Women's National Coalition: records 2002-10 (Wales Women's National Coalition Papers)
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